江蘇省徐州市2009屆高三第二次調(diào)研考試
化 學(xué) 試 題
注意事項(xiàng)
考生在答題前請認(rèn)真閱讀本注意事項(xiàng)及各題答題要求
1.本試題分試題卷和答題紙兩部分。試題卷8頁，答題紙2頁，共10頁。試題包含選擇題［第1題～第14題，共48分］、非選擇題［第15題～第21題（其中第21題為選做題，考生只要在A、B兩題中任選其中一題作答。如果兩題均作答，則以A題得分計(jì)入總分），共72分］兩部分。本次考試時(shí)間為100分鐘，滿分120分。
2．答題前，考生務(wù)必將自己的姓名、考試號等填寫在答題紙的指定位置。所有試題答案直接寫在答題紙上規(guī)定位置。在試卷或草稿紙上作答一律無效。考試結(jié)束，考生只交答題紙。
3.如有作圖需要，可用2B鉛筆作答，并請加黑加粗，描寫清楚。
可能用到的相對原子質(zhì)量：H―1 N―14 O―16 Na―23 S―32 Cl―35.5 Fe―56
選 擇 題
單項(xiàng)選擇題：本題包括8小題，每小題3分，共計(jì)24分。每小題只有一個(gè)選項(xiàng)符合題意。
1．《中華人民共和國食品安全法》已公布，將于今年6月1日起實(shí)施。下列做法符合食品安全要求的是
A．加工香腸時(shí)加入亞硝酸鈉以保持肉類新鮮
B．在食鹽中加適量的乳酸鋅以防止兒童缺鋅
C．制作膨化食品時(shí)需加入過量的膨松劑硫酸鋁銨
D．用福爾馬林（甲醛溶液）浸泡海產(chǎn)品使其長時(shí)間保鮮
研考試化學(xué)卷.files/image002.jpg)
2．下列化學(xué)用語正確的是
A．硝基苯的結(jié)構(gòu)簡式：
B．S2- 的結(jié)構(gòu)示意圖：研考試化學(xué)卷.files/image004.jpg)
研考試化學(xué)卷.files/image005.gif) |
C．丙烷的分子結(jié)構(gòu)模型示意圖：
D．16O與18O互為同位素，H216O、D216O、H218O、D218O互為同素異形體
3．設(shè)NA表示阿伏加德羅常數(shù)的值，下列說法不正確的是
A．1 mol α-氨基乙酸（甘氨酸）分子中存在10 NA對共用電子
B．
C．100mL 3 mol•L-1鹽酸與
D．在標(biāo)準(zhǔn)狀況下，
4．下列描述違背化學(xué)原理的是
A．NaHCO3溶液與NaAlO2溶液混合產(chǎn)生白色沉淀，說明酸性：HCO3-＞Al(OH)3
B．將SO2通入酸性高錳酸鉀溶液中，溶液褪色，說明SO2具有漂白性
C．濃硝酸在光照條件下變黃，說明濃硝酸不穩(wěn)定，生成有色產(chǎn)物能溶于濃硝酸
D．在KI溶液中加入氯化銀，一段時(shí)間后沉淀變成黃色，說明同溫度下Ksp(AgI)＜ Ksp(AgCl)
研考試化學(xué)卷.files/image010.gif)
5．下列裝置或操作不能達(dá)到實(shí)驗(yàn)?zāi)康牡氖?nbsp;
6．下列排列順序正確的是
A．固體的熱穩(wěn)定性：Na2CO3＞CaCO3＞NaHCO3
B．微粒半徑：Fe(OH)3膠粒＞K+＞C1-＞Na+
C．給出質(zhì)子的能力：CH3COOH＞C2H5OH＞H2O
D．氫化物的沸點(diǎn)：H2Se＞H2S＞H2O
X
Y
Z
W
7．右表是元素周期表的一部分。X、Y、Z、W均為短周期元素，X、W的質(zhì)子數(shù)之和為23。下列說法正確的是
A．X元素最多可形成五種氧化物
B．W元素的非金屬性比Z元素非金屬性弱
C．Z和X能以共價(jià)鍵結(jié)合形成一種無機(jī)非金屬材料
D．Y元素的最高價(jià)氧化物的水化物是含氧酸中酸性最強(qiáng)的
8．下列離子組在指定溶液中能大量共存的是
A．常溫時(shí)，在c(H+)=研考試化學(xué)卷.files/image012.gif)
的溶液：Na+、Fe3+、NO3-、Cl-
B．含大量Fe2+的溶液：Na＋、Mg2＋、H+、NO3-
C．含有大量Al3+的溶液：K+、Na+、AlO2-、SO42-
D．在c(H+)/c(OH-) ＝ 1×1013的溶液：NH4+、Mg2+、C1-、K+
不定項(xiàng)選擇題：本題包括6小題，每小題4分，共計(jì)24分。每小題有一個(gè)或兩個(gè)選項(xiàng)符合題意。若正確答案只包括一個(gè)選項(xiàng)，多選時(shí)，該題得0分；若正確答案包括兩個(gè)選項(xiàng)，只選一個(gè)且正確的得2分，選兩個(gè)且都正確的得滿分，但只要選錯(cuò)一個(gè)，該小題就得0分。
9．下列實(shí)驗(yàn)操作或?qū)?shí)驗(yàn)事實(shí)的敘述正確的是
①用酸性高錳酸鉀溶液可以鑒別苯和甲苯
②如果皮膚上不慎沾有苯酚，應(yīng)立即用酒精洗滌
③用pH試紙測得氯水的pH為2
④用稀硝酸清洗做過銀鏡反應(yīng)實(shí)驗(yàn)的試管
⑤少量的鈉、鉀、白磷通常保存在煤油中
⑥用瓷坩堝高溫熔融Fe(CrO2)2和Na2CO3的固體混合物
A．①③⑤ B．①②④ C．②④⑤ D．②⑤⑥
10．下列離子方程式書寫正確的是
A．足量澄清的石灰水與碳酸氫鈣溶液混合：Ca2+＋HCO3-＋OH-=CaCO3↓+H2O
B．用FeS除去工業(yè)廢水中的Hg2+：Hg2+＋S2- =HgS↓
C．向Fe(OH)3中加入HI溶液：Fe(OH)3＋3H+=Fe3+＋3H2O
D．向Ag(NH3)2OH溶液中加足量稀硝酸：Ag(NH3)2++
11．下圖是我國化學(xué)家近年來合成的兩種聚乙炔衍生物分子的結(jié)構(gòu)式。
研考試化學(xué)卷.files/image014.jpg)
下列說法不正確的是
A．A和B均能在一定條件下水解，且水解均生成兩種產(chǎn)物
B．A水解生成的高分子化合物的單體中所有碳原子共平面
C．B水解產(chǎn)生的氨基酸分子中有一個(gè)手性碳原子
D．A和B各1mol與熱堿液反應(yīng)，均最多消耗2n mol NaOH
12．下列溶液中各微粒的濃度關(guān)系正確的是
A．pH相等的①NH4Cl ②(NH4)2SO4 ③NH4HSO4溶液：c (NH4+)大小順序?yàn)棰?gt;②>③
B．pH相等的NaF與CH3COOK溶液：[c(Na＋)－c(F-)]>[c(K＋)－c(CH3COO-)]
C．0.2mo1?L-1的Na2CO3溶液：c(OH-)＝c(HCO3-)＋c(H+)＋
D．0.2 mo1?L-1 HCl與0.1 mo1?L-1 NaAlO2溶液等體積混合：
c(Cl-)> c(Na+)>c(Al3＋)>c(H＋)>c(OH－)
13．鉛蓄電池在現(xiàn)代生活中有廣泛應(yīng)用，其電極材料是Pb和PbO2，電解液是硫酸溶液。現(xiàn)用鉛蓄電池電解飽和硫酸鈉溶液一段時(shí)間，假設(shè)電解時(shí)溫度不變且用惰性電極，下列說法不正確的是
A．蓄電池放電時(shí)，每消耗0.1molPb，共生成0.1molPbSO4
B．電解池的陽極反應(yīng)式為：4OH-- 4e-==2H2O + O2↑
C．電解后，c(Na2SO4)不變，且溶液中有晶體析出
D．蓄電池中每生成1molH2O，電解池中就消耗1molH2O
14．在200 mL含Mg2+、Al3+、NH4+、H+、Cl-等離子的溶液中，逐滴加入5mol•L-1的氫氧化鈉溶液，所加氫氧化鈉溶液的體積(mL)與產(chǎn)生沉淀的物質(zhì)的量(mol)關(guān)系如下圖所示。
研考試化學(xué)卷.files/image015.gif)
下列敘述正確的是
A．x與y的差值為0.01 mol
B．原溶液中c(Cl-)=0.75 mol?L-1
C．原溶液的pH=1
D．原溶液中n(Mg2+)∶n(Al3+)=5∶2
非 選 擇 題
研考試化學(xué)卷.files/image017.jpg)
15．（10分）某校學(xué)生用如下圖所示裝置進(jìn)行實(shí)驗(yàn)，以探究苯與溴發(fā)生反應(yīng)的原理并分離提純反應(yīng)的產(chǎn)物。
請回答下列問題：
（1）冷凝管所起的作用為冷凝回流和 ，冷凝水從 口進(jìn)入（填“a”或“b”）。
（2）實(shí)驗(yàn)開始時(shí)，關(guān)閉K2、開啟K1和分液漏斗活塞，滴加苯和液溴的混合液，反應(yīng)開始。III中小試管內(nèi)苯的作用是 。
（3）能說明苯與液溴發(fā)生了取代反應(yīng)的現(xiàn)象是 。
（4）反應(yīng)結(jié)束后，要讓裝置Ⅰ中的水倒吸入裝置Ⅱ中。這樣操作的目的是 ，簡述這一操作的方法 。
（5）將三頸燒瓶內(nèi)反應(yīng)后的液體依次進(jìn)行下列實(shí)驗(yàn)操作就可得到較純凈的溴苯。
① 用蒸餾水洗滌，振蕩，分液；② 用5%的NaOH溶液洗滌，振蕩，分液；
③ 用蒸餾水洗滌，振蕩，分液；④ 加入無水CaCl2粉末干燥；
⑤ （填操作名稱）。
16.（8分）下列框圖表示各有關(guān)物質(zhì)之間的轉(zhuǎn)化關(guān)系，所有反應(yīng)物、生成物及溶液中的水均未標(biāo)出。已知常溫下D、E、F、H、L、N均為氣體；A的焰色反應(yīng)呈黃色；向B的溶液中滴加KSCN溶液，無明顯現(xiàn)象；1molB隔絕空氣分解得到F、G、H三種氧化物，其物質(zhì)的量均為1mol；F是易與血紅蛋白結(jié)合的物質(zhì)；J是現(xiàn)代社會(huì)中應(yīng)用最廣泛的金屬單質(zhì)。
研考試化學(xué)卷.files/image019.jpg) |
請回答下列題：
（1）B的化學(xué)式 ；H的電子式 。
（2）電解A溶液的離子方程式為 。
（3）D與E反應(yīng)可制得一種重要的化工原料，其反應(yīng)的現(xiàn)象是 。
（4）F與G反應(yīng)的化學(xué)方程式為 。
17．（10分）我國目前制備多晶硅主要采用三氯氫硅氫還原法、硅烷熱解法和四氯化硅氫還
原法。由于三氯氫硅還原法具有一定優(yōu)點(diǎn)，被廣泛應(yīng)用。其簡化的工藝流程如圖所示：
研考試化學(xué)卷.files/image020.gif) |
（1）制備三氯氫硅的反應(yīng)為：Si(s)＋3HCl(g) == SiHCl3(g)＋H2(g) ΔH=－210 kJ•mol-1。
伴隨的副反應(yīng)有：Si(s)＋4HCl(g) == SiCl4(g)＋2H2(g) ΔH=－241 kJ•mol-1。
SiCl4在一定條件下與H2反應(yīng)可轉(zhuǎn)化為SiHCl3，反應(yīng)的熱化學(xué)方程式為：
SiCl4(g)＋H2(g) == SiHCl3(g)＋HCl(g) ΔH= 。
（2）由純SiHCl3制備高純硅的化學(xué)反應(yīng)方程式為 。該生產(chǎn)工藝中可以循環(huán)使用的物質(zhì)是 （至少寫出兩種）。
（3）由于SiH4具有易提純的特點(diǎn)，因此硅烷熱分解法是制備高純硅很有發(fā)展?jié)摿Φ姆椒ā９I(yè)上廣泛采用的合成硅烷方法是讓硅化鎂和固體氯化銨在液氨介質(zhì)中反應(yīng)得到硅烷，化學(xué)方程式是 ；整個(gè)制備過程必須嚴(yán)格控制無水，否則反應(yīng)將不能生成硅烷，而是生成硅酸和氫氣等，其化學(xué)方程式為 ；整個(gè)系統(tǒng)還必須與氧隔絕，其原因是 。
18．（10分）煤化工是以煤為原料，經(jīng)過化學(xué)加工使煤轉(zhuǎn)化為氣體、液體、固體燃料以及各種化工產(chǎn)品的工業(yè)過程。
（1）將水蒸氣通過紅熱的碳即可產(chǎn)生水煤氣。反應(yīng)為：
研考試化學(xué)卷.files/image022.gif)
C(s)＋H2O(g) CO(g)＋H2(g) ΔH=＋131.3 kJ•mol-1，ΔS=＋133.7J•(K•mol) -1
①該反應(yīng)能否自發(fā)進(jìn)行與 有關(guān)；
②一定溫度下，在一個(gè)容積可變的密閉容器中，發(fā)生上述反應(yīng)，下列能判斷該反應(yīng)達(dá)到化學(xué)平衡狀態(tài)的是 （填字母，下同）。
a．容器中的壓強(qiáng)不變 b．1 mol H―H鍵斷裂的同時(shí)斷裂2 molH―O鍵
c．v正(CO) = v逆(H2O) d．c(CO)=c(H2)
（2）將不同量的CO(g)和H2O(g)分別通入到體積為2L的恒容密閉容器中，進(jìn)行反應(yīng)
CO(g)＋H2O(g) CO2(g)＋H2(g)，得到如下三組數(shù)據(jù)：
實(shí)驗(yàn)組
溫度/℃
起始量/mol
平衡量/mol
達(dá)到平衡所
需時(shí)間/min
H2O
CO
H2
CO
1
650
2
4
1.6
2.4
5
2
900
1
2
0.4
1.6
3
3
900
a
b
c
d
t
①實(shí)驗(yàn)1中以v(CO2) 表示的反應(yīng)速率為 。
②該反應(yīng)的逆反應(yīng)為 （填“吸”或“放”）熱反應(yīng)
③若實(shí)驗(yàn)3要達(dá)到與實(shí)驗(yàn)2相同的平衡狀態(tài)（即各物質(zhì)的質(zhì)量分?jǐn)?shù)分別相等），且t<3min，則a、b應(yīng)滿足的關(guān)系是 （用含a、b的數(shù)學(xué)式表示）。
（3）目前工業(yè)上有一種方法是用CO2來生產(chǎn)甲醇。一定條件下發(fā)生反應(yīng)：
研考試化學(xué)卷.files/image024.jpg)
CO2(g)＋3H2(g)研考試化學(xué)卷.files/image026.jpg)
CH3OH(g)＋H2O(g) ，右下圖表示該反應(yīng)進(jìn)行過程中能量(單位為kJ•mol-1)的變化。在體積為
中，充入1mol CO2和3mol H2，下列措施中能使
c (CH3OH)增大的是___________。
a．升高溫度
b．充入He(g)，使體系壓強(qiáng)增大
c．將H2O(g)從體系中分離出來
d．再充入1mol CO2和3mol H2
19．（12分）乙基香蘭素是當(dāng)今世界上最重要的合成香料之一，其結(jié)構(gòu)簡式如下圖所示。
（1）以下推測正確的是 （填字母）。
研考試化學(xué)卷.files/image028.jpg)
a．從分子結(jié)構(gòu)上看，它應(yīng)該屬于芳香烴
b．該物質(zhì)的一個(gè)分子內(nèi)含有一個(gè)碳氧雙鍵、三個(gè)碳碳雙鍵
c．1 mol該物質(zhì)最多能與4molH2發(fā)生加成反應(yīng)
d．該物質(zhì)能與碳酸鈉溶液反應(yīng)產(chǎn)生CO2氣體
（2） R物質(zhì)屬于乙基香蘭素的同分異構(gòu)體，其性質(zhì)如下：
研考試化學(xué)卷.files/image030.jpg)
研考試化學(xué)卷.files/image035.gif)
試寫出符合條件的R的同分異構(gòu)體的結(jié)構(gòu)簡式(任寫兩種) ：
；
。（3）X也是乙基香蘭素的同分異構(gòu)體，可以通過不同的反應(yīng)制得下列物質(zhì)。
請回答下列問題：
（Ⅰ）反應(yīng)①、②的反應(yīng)類型 、 ；
（Ⅱ）反應(yīng)③所需的試劑是 ；A的結(jié)構(gòu)簡式 ；
（Ⅲ）反應(yīng)④的化學(xué)方程式 。
20．(10分) Na2S2O3?5H2O（俗稱海波）是照相業(yè)常用的一種定影劑。工業(yè)上制得的Na2S2O3?5H2O晶體中可能含有Na2SO3。為測定某海波樣品的成分，稱取三份質(zhì)量不同的該樣品，分別加入相同濃度的硫酸溶液30 mL，充分反應(yīng)（Na2S2O3＋H2SO4=Na2SO4＋SO2↑＋S↓＋H2O）后濾出硫，微熱濾液使SO2全部逸出。測得有關(guān)實(shí)驗(yàn)數(shù)據(jù)如下表（氣體體積已換算為標(biāo)準(zhǔn)狀況）。
第一份
第二份
第三份
樣品的質(zhì)量/g
6.830
13.660
30.000
二氧化硫氣體的體積/L
0.672
1.344
2.688
硫的質(zhì)量/g
0.800
1.600
3.200
試計(jì)算：
（1）所用硫酸溶液的物質(zhì)的量濃度為 。
（2）樣品中n(Na2S2O3?5H2O)：n(Na2SO3)= 。
（3）某環(huán)境監(jiān)測小組用上述海波樣品配制含Na2S2O3 0.100 mol?L-1的海波溶液，并利用它測定某工廠廢水中Ba2+的濃度。他們?nèi)U水50.00 mL，控制適當(dāng)?shù)乃岫燃尤胱懔康腒2Cr2O7溶液，得BaCrO4沉淀；沉淀經(jīng)洗滌、過濾后，用適量的稀鹽酸溶解，此時(shí)CrO42-全部轉(zhuǎn)化為Cr2O72-；再加過量KI溶液，充分反應(yīng)后，用上述配制的海波溶液進(jìn)行滴定，反應(yīng)完全時(shí)，測得消耗海波溶液的體積為36.00 mL。已知有關(guān)反應(yīng)的離子方程式為：
①Cr2O72-
+ 6I- + 14H+ 2Cr3+ + 3I2 + 7H2O
②I2 + 2S2O32-
2I- + S4O62-
③I2
+ SO32- + H2O 2I- + SO42-
+ 2H+
則滴定過程中可用 作指示劑。計(jì)算該工廠廢水中Ba2+的物質(zhì)的量濃度。
21．選做題 本題有A、B兩題，分別對應(yīng)于“物質(zhì)結(jié)構(gòu)與性質(zhì)”和“實(shí)驗(yàn)化學(xué)”二個(gè)選修課程模塊的內(nèi)容，每題12分。請選擇其中一題作答，并把所選題目對應(yīng)字母后的方框涂黑。若兩題都作答，將按A題評分。
A．《物質(zhì)結(jié)構(gòu)與性質(zhì)》
均由兩種短周期元素組成的A、B、C、D化合物分子，都含有18個(gè)電子，它們分子中所含原子的數(shù)目依次為2、3、4、6。A和C分子中的原子個(gè)數(shù)比為1∶1，B和D分子中的原子個(gè)數(shù)比為1∶2。D可作為火箭推進(jìn)劑的燃料。
請回答下列問題：
（1）A、B、C、D分子中相對原子質(zhì)量較大的四種元素第一電離能由大到小排列的順序?yàn)?u> （用元素符號回答）。
（2）A與HF相比，其熔、沸點(diǎn)較低，原因是 。
（3）B分子的空間構(gòu)型為 形，該分子屬于 分子。（填“極性”或“非極性”）
研考試化學(xué)卷.files/image037.gif)
（4）C為一種綠色氧化劑，有廣泛應(yīng)用。請寫出Cu、稀H2SO4與C反應(yīng)制備硫酸銅的離子方程式
，該反應(yīng)中反應(yīng)物Cu原子的基態(tài)電子排布式為
。銅晶體中銅原子的堆積方式為面心立方堆積，右圖是銅晶體一個(gè)晶胞的示意圖，則晶胞中含
個(gè)銅原子。
（5）D分子中心原子的雜化方式是 ，由該原子組成的單質(zhì)分子中包含
個(gè)π鍵，與該單質(zhì)分子互為等電子體的常見分子的分子式為 。
B．《實(shí)驗(yàn)化學(xué)》
乙酰水楊酸（阿斯匹林）是一種常用的解熱鎮(zhèn)痛、抗風(fēng)濕類藥物，廣泛應(yīng)用于臨床治療和預(yù)防心腦血管疾病，近年來還不斷發(fā)現(xiàn)它的新用途，它可由水楊酸和乙酸酐反應(yīng)得到。
研考試化學(xué)卷.files/image039.jpg) |
在生成乙酰水楊酸的同時(shí)，水楊酸分子間也能發(fā)生縮合反應(yīng)，生成少量聚合物(副產(chǎn)物)。合成乙酰水楊酸的實(shí)驗(yàn)步驟如下：
① 向150mL干燥錐形瓶中加入
② 減壓過濾，用濾液淋洗錐形瓶，直至所有晶體被收集到布氏漏斗中。抽濾時(shí)用少量冷水洗滌晶體幾次，繼續(xù)抽濾，盡量將溶劑抽干。然后將粗產(chǎn)品轉(zhuǎn)移至表面皿上，在空氣中風(fēng)干。
③ 將粗產(chǎn)品置于100mL燒杯中，攪拌并緩慢加入25mL飽和碳酸氫鈉溶液，加完后繼續(xù)攪拌2～3分鐘，直到?jīng)]有二氧化碳?xì)怏w產(chǎn)生為止。過濾，用5～10mL蒸餾水洗滌沉淀，合并濾液于燒杯中，不斷攪拌，慢慢加入15mL 4mol•L -1鹽酸，將燒杯置于冷水中冷卻，即有晶體析出。抽濾，用冷水洗滌晶體1～2次，再抽干水分，即得產(chǎn)品。
請回答下列問題：
（1）通常乙酸酐在使用前需重新蒸餾，原因是 。
（2）第①步中，要控制反應(yīng)溫度在85～90℃，應(yīng)采用_________ 加熱方法，水楊酸與乙酸酐的反應(yīng)過程中，濃硫酸的作用是 。
(3) 在第②步中，用冷水洗滌晶體，其目的是___________________________；
洗滌方法是 。
(4) 第③步中，加入碳酸氫鈉的作用是____________________
加入鹽酸的作用是________________________
2009屆高三第三次調(diào)研考試
江蘇省徐州市2009屆高三第二次調(diào)研考試
英 語 試 題
說明：1．本試卷共共分5部分，滿分120分，考試時(shí)間120分鐘。
2．在答題卡的相應(yīng)位置填寫姓名、考號等，密封線內(nèi)不要答題；
3．請將所有答案按照題號填涂或填寫在答題卡相應(yīng)的答題處，否則不得分。
第一部分 聽力（共兩節(jié)，滿分20分）
做題時(shí), 先將答案劃在試卷上。錄音內(nèi)容結(jié)束后, 你將有兩分鐘的時(shí)間將試卷上的答案轉(zhuǎn)涂到答題卡上。
第一節(jié)（共5小題：每小題1分，共5分）
聽下面5段對話。每段對話后有一道小題，從每題所給的A、B、C三個(gè)選項(xiàng)中選出最佳選項(xiàng)。聽完每段對話后，你將有10秒鐘的時(shí)間來回答有關(guān)小題和閱讀下一小題。每段對話你將聽一遍。
1. Where does the woman live now?
A. In
2. What was the climate like where the old couple lived?
A. It was very rainy. B. It was very warm. C. It was very snowy.
3. What do we know from the conversation?
A. Both of them got good marks in the exam. B. One of them spilt the milk.
C. Either of them got low marks in the exam.
4. Why won’ t the woman order dessert?
A. She thinks the dessert is too expensive. B. She doesn’ t want to gain weight.
C. She is afraid of dropping the dessert on her clothes.
5. Why did the woman get a new job in another country?
A. Because she hated to work with the man here.
B. Because she didn’ t like the culture. here.
C. Because she wanted to experience a new culture.
第二節(jié)（共15小題：每小題1分，共15分）
聽下面6段對話或獨(dú)白。每段對話或獨(dú)白后有幾道小題，從每題所給的A、B、C三個(gè)選項(xiàng)中選出最佳選項(xiàng)。聽每段對話或獨(dú)白前，你將有5秒鐘的時(shí)間閱讀每小題。聽完后，每小題將給出5秒鐘的做答時(shí)間。每段對話或獨(dú)白你將聽兩遍。
聽第6段材料，回答第6―8題。
6. Why does the man think it is bad to take a taxi at first?
A. Because these suitcases are not heavy. B. Because there are just a few suitcases.
C. Because the traffic is heavy now.
7. How far is it to get there?
A. Fifty minutes on foot. B. Fifteen minutes on foot. C. Fifteen minutes by taxi.
8. How do they probably go there at last?
A. By bus. B. On foot. C. By taxi.
聽第7段材料, 回答第9至11題。
9. People who relax at home often ________.
A. agree to offer help actively B. refuse to help other people
C. offer help against their own will
10. Why do people offer help when they are not willing to?
A. They are so kind that they don’t want to see people in trouble.
B. They are afraid that their refusal might hurt their good relationship.
C. They can’t help offering help to others out of habit.
11. What should people do when facing such problems?
A. Never refuse the people in need of help.
B. Always say “no” to the people who need help.
C. Refuse some requests when necessary.
聽第8段材料, 回答第12至14題。
12. How does the man book his ticket?
A. On the Internet. B. Through a friend. C. On the phone.
13. Which city is the man leaving for?
A. Houston.
B. Chicago.
C. A city in
14. When is the man returning?
A. On May 5. B. On May 2. C. On May 6.
聽第9段材料, 回答第15至17題。
15. Where does this conversation take place?
A. In a restaurant. B. At an interview. C. At a schoo1.
16. Why does the man want a new job?
A. He is fired. B. He likes computer. C. He wants more money.
17. What will probably happen to the man next?
A. He will be turned down by the woman. B. He will work as a computer programmer.
C. He will work as a cameraman.
聽第10段材料, 回答第18至20題。
18. What
do
A. To open many new factories. B. To permit rapid industrialization.
C. To fire workers with specific skills.
19. What do the factory owners do to get maximized profits?
A. They make full use of automation if possible.
B. They hire as many workers as possible.
C. They train workers for specific factory jobs.
20. Which aspect does the speaker focus on?
A. The advantages of rapid industrialization. B. The problems of rapid industrialization.
C. The progress of rapid industrialization.
第二部分 英語知識(shí)運(yùn)用（共兩節(jié)，滿分35分）
第一節(jié) 單項(xiàng)填空（共15小題；每小題1分，滿分15分）
從A、B、C、D四個(gè)選項(xiàng)中，選出可以填入空白處的最佳選項(xiàng)，并在答題卡上將該項(xiàng)涂黑。
21. Graduates of 2009 share ______ fate of entering the work force at a bad time, when the world is sinking deeper into ______ financial crisis.
A. the ；the B. a ；the C. a ；不填 D. the ；a
22. ---- Do you know why the sun looks much bigger on the horizon?
---- Well, well, ______. I’ ve never read about that.
A. you really have me there B. that depends
C. I can’t tell you D. there is some doubt
23. Each member country of WTO must ______ its laws and regulations and compete on the principle of fairness and co-operation.
A. cater to B. correspond to C. relate to D. submit to
24. ______ sculpture is to a block of marble, education is to a human soul.
A. That B. Which C. What D. Where
25. ---- Why didn’t you pick up the MP4?
---- I ______ it, but I didn’t carry that much money.
A. could buy B. should buy C. must have bought D. could have bought
26. ---- It is reported in the local newspaper that the murderer was caught in a small town.
---- ________.
A. Justice has long arms B. One false move may lose the game
C. Lies have short legs D. Kings go mad, and the people suffer for it
27. ---- Mr. Wang got the first prize in the singing competition last week.
---- Oh. That’s what he ______ for years.
A. had been expecting B. has expected C. expected D. has been expecting
28. We finally managed to make the customers ______ of the quality of the vehicle.
A. to convince B. convincing C. convince D. convinced
29. ---- I wonder ______ Mr. Black changed his mind to take part in the movement.
---- After he listened to the speech by Mr. King.
A. when was that it B. when was it that C. when that was D. when it was that
30?You can make a complaint to the local government ______ you are happy with the way things are.
A. unless B. if C. once D. as
31.
Hillary Clinton arrived in
A. marked B. having marked C. marking D. to mark
32. Despite what I’d been told about the native people’s attitude towards strangers, ______ did I come across any rudeness.
A. in no time B. at no time C. in any time D. at any time
33. Although I’ve never worked for a bank before, I feel quite ______ there because I’m used to dealing with figures.
A. at peace B. at home C. at sea D. at will
34. ---- I don’t want to move to that city. It is heavily polluted.
---- Pollution is common. The city here is ______.
A. no less clean B. no clean C. no cleaner D. not less clean
35. Pointing to the house on ______ roof grew lots of bush, the old man told me that was ______
I would stay.
A. its ；what B. whose ；what C. whose ；where D. its ；where
第二節(jié) 完型填空（共20小題；每小題1分，滿分20分）
閱讀下面短文，掌握其大意，然后從36―55各題所給的四個(gè)選項(xiàng)（A、B、C、D）中，選出最佳選項(xiàng)，并在答題卡上將該項(xiàng)涂黑。
Dear son,
The day that you see me old and I am already not in good health, have patience and try to understand me.
If I get dirty when eating, if I can not dress, have patience and remember the hours I 36 teaching it to you. If, when I speak to you, I 37 the same things thousand and one times, do not 38 me, listen to me. When you were small, I had to read to you thousand and one times the same story 39 you got to sleep. When I do not want to have a 40 , neither shame me nor scold me. Remember when I had to chase you with thousand excuses I 41 , in order that you wanted to bathe. When you see my 42 little about new technologies, give me the necessary time and do not look at me with your mocking(嘲弄) smile. I taught you 43 to do so many things: to eat good, to dress well, to confront life…. When at some moment I lose the memory or the 44 of our conversation, let me have the necessary time to remember, and if I cannot do it, do not become nervous, as the most important thing is not our conversation but surely to be with you and to have you 45 to me.
If ever I do not want to eat, do not force me. I know well 46 I need to and when not. When my 47 legs do not allow me to walk, give me your 48 , the same way I did when you gave your first 49 . And when someday I say to you that I do not want to 50 any more ---- that I want to rest forever, do not get angry. Someday you will understand.
Try to understand that my age is not lived but survived. Some day you will discover that, 51 my mistakes, I always wanted the 52 thing for you and that I tried to prepare the way for you. You must not feel sad, angry or impotent(無可奈何) for seeing me 53 you. You must be next to me, try to understand me and to help me as I did it when you 54 living. Help me to walk, help me to end my way with love and 55 . I will pay you by a smile and by the immense love I have had always for you.
I love you, Son.
Your father
36. A. paid
B. spent
C. cost
D. took
37. A. praise
B. think
C. repeat
D. criticize
38. A. interrupt
B. disturb
C. look
D. avoid
39. A. when
B. after
C. since
D. until
40. A. rest
B. word
C. shower
D. sleep
B. invented
C. noticed
D. assumed
42. A. knowing
B. fearing
C. enjoying
D. consulting
43. A. what
B. when
C. how
D. why
44. A. news
B. attitude
C. material
D. thread
45. A. talking
B. listening
C. responding
D. appealing
46. A. where
B. how
C. that
D. when
47. A. tired
B. short
C. long
D. strong
48. A. leg
B. ear
C. hand
D. mind
49. A. step
B. pace
C. laugh
D. cry
50. A. talk
B. live
C. write
D. sleep
51. A. though
B. since
C. while
D. despite
52. A. last
B. first
C. best
D. most
53. A. near
B. behind
C. below
D. against
54. A. made
B. started
C. earned
D. found
55. A. mercy
B. care
C. excuse
D. patience
第三部分：閱讀理解（共15小題；每小題2分，滿分 30分）
閱讀下列短文，從每題所給的四個(gè)選項(xiàng)（A、B、C和D）中，選出最佳選項(xiàng)，并在答題卡上將該項(xiàng)涂黑。
A
Kenya wants to organize a major
international conference to discuss how to fight piracy(海盜) off the coast of Somalia. The conference
may also deal with ways to rescue
Kenyan Foreign Minister Moses
Wetangula says the world cannot end piracy and civil war without dealing with
Somali pirates operate in the
Indian Ocean and the
Pirates hijacked the Sirius Star
off the coast of
The tanker Sirius Star, at three hundred thirty meters long, is the biggest ship ever known to have been captured by pirates. It also happened farther south than most attacks, and farther out at sea ---- more than eight hundred kilometers from land.
研考試――英語.files/image002.jpg)
The ship was headed for the
Somali pirates generally do not steal goods or kill hostages. They are believed to be holding seventeen ships with about three hundred crew members. Among the ships is a Ukrainian vessel hijacked(劫持) in September with a load of military weapons including tanks.
The increase in piracy is raising
the cost of insuring ships. Also, oil from the Middle East and exports from
Some of the world’s heaviest
shipping traffic passes the Somali coast. But major shipping companies have
begun to consider new routes. One of the world’s biggest shippers, A.P, Moeller
Maersk, says it will avoid the
American and other foreign navy
ships are now watching for pirates. This week the Indian Navy destroyed a
heavily armed “mother ship” in the
56.
According to the passage, which of the following is the key to solving the
piracy in
A. Providing lots of money. B. Ending Civil war.
C. Supplying enough food.
D. Handling
57. Somali pirates do the following things except that _______.
A. they demand money B. they hold the ships with crew
C. they kill some of the hostages D. they hijack ships with military weapons
58. What can we infer from the passage?
A. The cost of ship transport is decreasing.
B. The routes of some ships might change.
C. Nothing has been done to fight against the piracy.
D. The Suez Canal is of no
importance to
B
ACTeen-Acting for Teens
The nation’s first on-camera acting program developed for teens(ages 13―15, 16―20). Now celebrating our 30th year. June, July, August, or。Saturday summer academies offer full or part-time curriculum. 14 + electives, including film & television acting, theater, musical theater, auditioning, Shakespeare, speech ＆ voice, movement, script writing.
Working grades, small classes(12 maximum per workshop). Safe, convenient location. Application required. Out of town applicants may submit long distance application.
Cost/Week: $500一$649
Indianhead Ranch
Sharpen your H unting Skills over
one or two weeks at Indianhead Ranch in
Cost/Week: $1000一$1999
Six-Day Adventure Camps
We offer 8 six-day adventure camps
for teens l1 to 13. The kids go stay in rustic cabins at our camping site in
Two-Week Adventure Camps
We also offer 4 two-week adventure camps for teens 14 to 17. The teens will go on an adventure each day and then come back to our quaint Adventure Lodge.
Cost/Week: $650
International ESL Camp
The site is in close proximity to
Cost/Week: $650一$999
59. According to the passages, which camp offers hunting skills?
A. Vermont Adventure Camps. B. Indianhead Ranch.
C. Acting for Teens. D. International ESL Camp.
60. Which of the following statements about ACTeeen is TRUE?
A. Applicants out of town cannot submit.
B. There i s no need for application to the camp.
C. The camp lasts until September.
D. Its curriculum includes script writing.
61. If Tom plans to send his 4 children to join Six-Day Adventure Camps, how much should he pay?
A. 2,340. B. 2,600. C. 260. D. 2,860.
C
It happened one morning 20 years ago. A British scientist Alec Jeffrey came across DNA fingerprinting: He identified the patterns of genetic material that are unique to almost every individual. His discovery changed everything from the way we do criminal investigations to the way we decide family law. But the professor of genetics at the University of Leicester, UK, is still surprised, and a bit worried, by the power of the technology he released upon the world.
The patterns within DNA are unique to each individual, except identical twins, who share the same pattern. The ability to identify these patterns has been used to convict(證明…有罪) murderers and to clear people who are wrongly accused. It is also used to identify the victims of war and settle disputes over who is the father of a child.
Jeffrey said he and his colleagues made the discovery by accident while tracking genetic variations(變異). But, within six months of the discovery, genetic fingerprinting had been used in an immigration case, to prove that an African boy really was his parents’ son.?In 1986, it was used for the first time in a British criminal case: It cleared one suspect after being accused of two murders and helped convict another man.
DNA testing is now very common. In
DNA testing is not an unfailing proof of identity. Still, it is considered a reasonably reliable system for determining the things it is used for. Jeffrey estimates the probability of two individuals’ DNA profiles matching in the most commonly used tests at one in a billion.
62. According to the text, DNA testing can NOT be used in _______ .
A. doing criminal investigations B. deciding faraily law
C. clearmg wrongly accused people D. telling twins apart
63. DNA samples are not popular with all the people because _______ .
A. the government in
B. the US and
C. DNA samples can be used to harm a person’s privacy
D. DNA testing is too expensive and dangerous now
64. Where will you most probably find this article?
A. In a guidebook. B. In a storybook.
C. In a science fiction. D. In a scientific magazine.
65. Which is the best title for the passage?
A. Discovery of DNA testing by Jeffery B. Practice of DNA testing in court
C. DNA testing in the present situation D.Benefits and side effects of DNA testing
D
In this voyage I visited my new colony on the island, saw the Spaniards(西班牙人), had the whole story of their lives and of the villains(罪犯) I left there; how at first they treated the poor Spaniards badly,?how they afterwards agreed, disagreed, unired, separated, and how at last the Spaniards were forced to use violence with them; how they gave in to the spaniards, how honestly the Spaniards used them ---- a history, if it were entered into, as full of variety and wonderful accidents as my own part ---- particularly, also, as to their battles with the Caribbeans, who landed several times upon the Island, and as to the improvement they made upon the Island itself, and how five of them made an attempt upon the main land, and brought away eleven men and five women prisoners, by which, at my coming, I found about twenty young children on the Island.
Here I stayed bout 20 days, left
them supplies of all necessary things, and particularly of arms, powder, shot,
cloths, tools, and two workmen, which I brought from
Besides this, I shared the
From then
on I landed the Brazils, from where I sent a bark, which I bought there, with
more people to the island; and in it, besides other supplies, I sent seven
women, being such persons as I found proper for service, or for wives to such
as would take them. As to the Englishmen, I promised them to send them some
women from England, with a good cargo(船貨)
of necessaries, if they would apply themselves to planting ---- which I
afterwards could not perform. And the fellows proved very honest and diligent
after they were mastered and had their properties set apart for them. I sent
them also from the
But all these things, with an
account how 300 Caribbeans came and invaded(入侵)
them, and ruined their plantations, and how they fought with that whole number
twice, and were at first defeated, and one of them killed; but at last a storm
destroying most of their enemies’ boats, they destroyed almost all the rest,
and renewed and recovered the possession of their plantation, and still lived
upon the
All these things, with some very surprising incidents in some new adventures of my own, for ten years more, I may perhaps give a further account of the story.
66. From Paragraph l, we know _______ .
A. the Spaniards were always getting along well with the villains
B. the Spaniards were always the rulers of the island
C. the Spaniards and the villains both ruled the island peacefully
D. the Spaniards and the villains once had battles witll each other
67. In Paragraph 2, the place where I stayed was probably ________.
A. a wild island B. a deserted downtown
C. a primitive supermarket
D. a
68. The underlined word “respectively” in the third paragraph probably means ______ .
A. separately B. particularly C. specially D. surprisingly
69. The writer of the story once went to _______.
A.
C.
70. From the story, we can judge the Writer might be _______ .
A. an invader B. a carpenter C. an adventurer D. a prisoner
第四部分 任務(wù)型閱讀（共10小題；每小題1分，滿分10分）
認(rèn)真閱讀下面短文，并根據(jù)所讀內(nèi)容在文章后表格中的空格里填入最恰當(dāng)?shù)膯卧~。
(注意：每空填1個(gè)單詞。)
“BANG! BANG!” Setting off firecrackers(爆竹), which has been the most typical custom on the Spring Festival, is the happiest part of the Festival for most Chinese kids. They light the fuse(導(dǎo)火線) nervously, run away in a hurry, cover their ears with their hands and watch the colorful display with a big smile on their faces. Faced with the beautiful scene, they feel they are the happiest ones in the world as if they had never had a more exciting experience.
While setting off firecrackers can
bring kids so much fun, these firecrackers can also be dangerous. Therefore,
many Chinese big cities including
This year good news came for teens in Beij ing. The ban on firecrackers was cancelled on September 9, 2008. It will add much fun to the coming Spring Festival in tile capital. Hearing the news, many kids were wild with joy.
According to Chinese custom, lighting firecrackers is a must during the Spring Fesrival. People believe the sound of the firecrackers drives away demons(惡魔) and bad luck for the coming year. Their beautiful colours and sound also bring much excitement during this most important traditional Chinese festival.
Since the ban, people complained that the Spring Festival was too quiet and not traditional enough. Children lost the fun and grown-ups lost their childhood memories.
Some even worried that if the ban continued, the next generation would only know the custom of lighting firecrackers through books. This would be a great loss for tradition.
Everybody knows that we can’t give
up eating for the slight risk of choking(因噎廢食).
So in recent years, many cities have resumed the old custom at the request of
local residents. This year
However, every year there are kids injured by setting off fireworks in a dangerous way. So while enjoying yourself, please bear safety in mind.
Don’t light fireworks among crowds, inside a bottle or with a part of your body right over it.
No matter how much fun firecrackers are, the most important thing is to keep away from danger. We wish every kid an exciting and safe Spring Festival!
Title：Firecrackers back in
71) △
for setting off firecrackers
☆I(lǐng)t is the most typical custom of the Chinese.
☆The sound of the firecrackers is 72) △ to drive away demons and bad luck.
☆Their beautiful colours and sound also make people 73) △ .
Fun for kids
☆Feeling nervous and running away 74) △ when lighting the fuse
☆Covering the ears with hands and 75) △ the colourful display joyfully
76) △ on the ban
☆I(lǐng)t is very dangerous for people and their properties.
☆I(lǐng)ts noise and smoke cause heavy 77) △ .
Complaints about the ban
☆Much fun for kids will be 78) △ .
☆I(lǐng)t’s difficult for grown-ups to remember their childhoods.
Return of firecrackers
☆The government 79) △ the ban on Septmnber 9, 2008.
☆I(lǐng)f taking proper 80) △
measures,
研考試――英語.files/image004.jpg)
第五部分 書面表達(dá) （滿分25分）
研考試――英語.files/image006.jpg)
法國一家拍賣公司于今年2月25日在巴黎公開拍賣從中國掠奪的鼠首和兔首銅像, 此舉激起中國人民的強(qiáng)烈憤慨。請你根據(jù)下表提示, 用英語寫一篇短文。
文物背景
1.鼠首和兔首銅像制作于清代, 是圓明園諸多裝飾品之一；
2.1860年, 英法聯(lián)軍火燒圓明園, 搶走包括鼠首和兔首銅像等在內(nèi)的大量文物。
文物事件
1.今年二月在巴黎公開拍賣；
2.中國政府堅(jiān)決反對, 要求按國際法無償歸還；
3.法國公司一意孤行；
4.中國人民積極行動(dòng), 采取措施阻止拍賣。
你的感想
(請考生談?wù)剬Υ耸碌目捶? 列舉兩至三條)
注意: 1.對所給要點(diǎn), 逐一陳述, 可適當(dāng)增加細(xì)節(jié), 使其連貫, 不簡單翻譯。
2.詞數(shù): 150左右。開頭已給出, 不計(jì)入總詞數(shù)。
3.參考詞匯. auction n. & vt. 拍賣relic [C] n.文物, 遺物
Last month in
…
江蘇省徐州市2009屆高三第二次調(diào)研考試
英 語 試 題 參 考 答 案
聽力：01―05 ACCBC 06―10 CBCCB 11―15 CCBAB 16―20 CABAB
單選：21―25 DADCD 26―30 AADDA 31―35 CBBCC
完形：36―40 BCADC 41―45 BACDB 46-50 DACAB 51-55 DCABD
閱讀 (A)56―58 DCB (B)59―61 BDA (C)62―65 DCDD (D)66―70 DAABC
填空：71. Reasons 72. believed/thought/supposed/expected 73. excited/thrilled/happy/joyful
74. hurriedly/quickly 75. watching 76. Factors 77. pollution 78. lost/gone/missing
79. cancelled 80. safety
表達(dá)：One Possible version:
Last month in
As is known to all, the two brone animal heads were
made during the Qing Dynasty to decorate Yuanmingyuan. In 1860, the British and
French troops broke into
The Chinese government is strongly against
this auction and has repeatedly asked for the free return of them according to
the international laws. At the same time, the Chinese people have taken
actions, too. Some people even flew to
In my opinion, the auction should be strongly condemned. Not
only has it hurt the feelings of the Chinese people but also brought
shame to
附01：書面表達(dá)評分標(biāo)準(zhǔn)
江蘇省徐州市2009屆高三第二次調(diào)研考試
政治試題
注意事項(xiàng)：
1．本試卷共8頁，包含選擇題(第1題-第33題，共33題)、非選擇題(第34題-第37題，共4題，其中第36題為選做題)兩部分。本卷滿分l20分，考試時(shí)間為100分鐘。考試結(jié)束后，請將答題卷和答題紙一并交回。
2．答題前，請務(wù)必將自己的姓名、準(zhǔn)考證號、座位號用0．5毫米黑色字跡簽字筆填寫在答題卷及答題紙上。
3．作答選擇題必須用28鉛筆把答題紙對應(yīng)題目的答案標(biāo)號涂黑。如需改動(dòng)，請用橡皮擦干凈后，再選涂其它答案。作答非選擇題必須用書寫黑色字跡的0．5毫米的簽字筆寫在答題卷上的指定位置，在其它位置作答一律無效。
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